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单词 Sigma bond
释义

Sigma bond

原声例句
Crash Course 综合篇

This straightforward sort of bond is called a sigma bond.

这种简单的债券称为 sigma 债券。

化学 Crash Course

Double bonds consist of a sigma bond and a pi bond.

双键由西格玛键和π键组成。

Crash Course 综合篇

The sp orbital, the one that forms the sigma bonds here, is linear.

在这里形成西格玛键的 sp 轨道是线性的。

化学 Crash Course

That pi bond bridges the sigma bond, locking it in place.

那个 pi 键桥接 sigma 键,将它锁定到位。

Crash Course 综合篇

As they come together for the bond, the sigma bonds will occur between the hybridized orbitals.

当它们聚在一起形成键时, σ键将出现在杂化轨道之间。

化学 Crash Course

Single bonds, also called sigma bonds, are pretty simple, and carbon atoms attached by them can rotate around the bond freely.

单键,也称为西格玛键,非常简单,它们所附着的碳原子可以围绕键自由旋转。

化学 Crash Course

The triple bonds in alkynes, meanwhile, are composed of 1 sigma bond and 2 pi bonds for a total of 3 bonds.

同时,炔烃中的三键由 1 个 sigma 键和 2 个 pi 键组成,总共 3 个键。

Crash Course 综合篇

This is because the carbon atoms in diamonds share sigma bonds, not pi bonds, which doesn't allow the electrons much freedom of movement.

这是因为钻石中的碳原子共享 sigma 键, 而不是 pi 键,这不允许电子有太多的运动自由度。

化学 Crash Course

Pi bonds are significantly more unstable than sigma bonds, so double and triple bonds are pretty easy to break, opening the doors for some good chemistry.

Pi 键明显比 sigma 键不稳定,因此双键和三键很容易断裂, 为一些良好的化学反应打开了大门。

化学 Crash Course

These occur when an atom is either triple bonded to another atom or is double bonded to 2 atoms. The sp orbital, the one that forms the sigma bonds here, is linear.

当一个原子与另一个原子形成三键或与 2 个原子形成双键时, 就会发生这种情况。在这里形成西格玛键的 sp 轨道是线性的。

Crash Course 综合篇

Just to note to avoid confusion: polyethylene has that " -ene" sound in it, right, but it's not an alkene because all those double bonds get broken to form new sigma bonds.

请注意以避免混淆:聚乙烯中有“-ene” 的发音,对吧,但它不是烯烃,因为所有这些双键都会断裂形成新的 sigma 键。

中文百科

Σ键

两个原子间σ键电子云
 enlace σ entre dos átomos: localización de la densidad electrónica.
Orbitales electrónicos atómicos y moleculares, mostrando entre otros al enlace sigma entre dos orbitales atómicos tipo s y un enlace sigma entre dos orbitales atómicos tipo p.
1sσ* antibonding molecular orbital in H2 with nodal plane

σ键是价键理论和分子轨道理论中一种化学键的名称。由两个相同或不相同的原子轨道沿轨道对称轴方向相互重叠而形成的共价键,叫做σ键。一般的“单键”都属于这种σ键,比如C-H, O-H, N-H, C-C, C-Cl等等。

由两个相同或不相同的原子轨道沿轨道对称轴方向相互重叠而形成的共价键,叫做σ键。σ键是原子轨道沿轴方向重叠而形成的,具有较大的重叠程度,因此σ键比较稳定。σ键是能围绕对称轴旋转,而不影响键的强度以及键跟键之间的角度(键角)。根据分子轨道理论,两个原子轨道充分接近后,能通过原子轨道的线性组合,形成两个分子轨道。其中,能量低于原来原子轨道的分子轨道叫成键轨道,能量高于原来原子轨道的分子轨道叫反键轨道。以核间轴为对称轴的成键轨道叫σ轨道,相应的键叫σ键。以核间轴为对称轴的反键轨道叫σ*轨道,相应的键叫σ*键。分子在基态时,构成化学键的电子通常处在成键轨道中,而让反键轨道空着。

英语百科

Sigma bond Σ键

σ bond between two atoms: localization of electron density
1sσ* antibonding molecular orbital in H2 with nodal plane

In chemistry, sigma bonds (σ bonds) are the strongest type of covalent chemical bond. They are formed by head-on overlapping between atomic orbitals. Sigma bonding is most simply defined for diatomic molecules using the language and tools of symmetry groups. In this formal approach, a σ-bond is symmetrical with respect to rotation about the bond axis. By this definition, common forms of sigma bonds are s+s, pz+pz, s+pz and dz+dz (where z is defined as the axis of the bond). Quantum theory also indicates that molecular orbitals (MO) of identical symmetry actually mix or hybridize. As a practical consequence of this mixing of diatomic molecules, the wavefunctions s+s and pz+pz molecular orbitals become blended. The extent of this mixing (or hybridization or blending) depends on the relative energies of the MO's of like symmetry.

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更新时间:2025/6/20 22:28:49