Dinitrogen tetroxide

Dinitrogen tetroxide, commonly referred to as nitrogen tetroxide, is the chemical compound N2O4. It is a useful reagent in chemical synthesis. It forms an equilibrium mixture with nitrogen dioxide.
Dinitrogen tetroxide is a powerful oxidizer that is hypergolic (spontaneously reacts) upon contact with various forms of hydrazine, which makes the pair a popular bipropellant for rockets.